本研究團隊過去已成功發展摩擦帶電機制成為動態監控金屬薄膜磨潤特性的新方法，並且發現不管是就靈敏性或判別性之考量，上述此種新方法均優於傳統以摩擦係數監控的方式，但卻因導電特性之限制而只侷限在導體對導體材料之配對。因此，本研究係進一步利用往復摩擦試驗機暨量測系統，動態同時量測摩擦界面之接觸電阻及摩擦係數對應於滑動距離之連續變化，以監控TiO2 薄膜破裂時機對接觸電阻之影響，並依據接觸電阻之變化而動態判別界面之化學反應物。同時量測磨耗損失量及以SEM 觀察微米級材料轉移現象，以詳細研究鈦與二氧化鈦薄膜間之磨潤行為。綜合實驗結果可發現接觸電阻之動態變化具有發展成為監控Ti 及TiO2薄膜材料之磨潤性能及判別界面間化學反應物的發展潛力。The novel method of using continuoustribo-electrification variations to monitor thedynamic tribological properties betweenmetal films has been applied successfully. The method was shown to produceclear and strong signals, superior tomonitoring continuous friction coefficient variations. However, the above method wasonly shown to be suitable for the testedmaterial pairs that were studied.In this paper, the method was improvedand applied to monitoring the dynamictribological properties between titaniumoxide (TiO2) films in the friction process.The experiment was conducted on apurposed-designed friction tester with asuitable measuring system. In order toinvestigate the tribological property oftitanium (Ti) sliding against Ti with TiO2films in detail, the continuous variations ofelectrical contact resistance and frictioncoefficient were measured for monitoring theonset of film rupture between the TiO2 filmsand the chemical reactions between theinterfaces. Wear loss was measured by anaccuracy balance and scan electronmicroscopy was used to observe themicrostructures and of material transfer.The experiments demonstrated that thenovel method of using electrical contactresistance variations has great potential formonitoring the dynamic tribologicalproperties and the chemical reactions oftitanium specimens.